The Chemistry of Caliche: Calcium Carbonate (CaCO3) Self-Hardening Mechanics
Caliche forms over geological epochs in arid and semi-arid climates where rainwater dissolves calcium ions from upper soils and redeposits them in lower soil horizons as calcium carbonate (CaCO3) crystals. In a roadbed, high-grade caliche containing 40% to 70% CaCO3 exhibits pozzolanic self-cementing behavior. When wetted to optimum moisture and compacted under heavy vibratory and pneumatic equipment, the dissolved calcium carbonate recrystallizes into mineral bridges that lock limestone and sand particles into a rigid, rock-like pavement slab.